Call us Today
(888) 846-4937
Email us Today
info@destinymarketingsolutions.com
Written by: Leonard Parker | solar news | March 31, 2021
In order to enable large-scale hydrogen production using solar energy, particulate photocatalysts are being researched as a simple and cost-effective solution to splitting water into hydrogen and oxygen. It is necessary to develop a photocatalyst that can efficiently use visible light, which accounts for a large part of solar energy, in the water decomposition reaction.
Barium tantalum oxynitride (BaTaO2N) is an oxynitride semiconductor material that absorbs visible light up to 650 nm and has a band structure capable of decomposing water into hydrogen and oxygen. Until very recently, it had not been possible to load BaTaO2N granules with co-catalyst fine particles, which are reaction active sites, with good adhesion and high dispersion.
In this study led by the Research Initiative for Supra-Materials of Shinshu University, the co-catalyst fine particles were found to be highly dispersed on the surface of the single crystal fine particles of BaTaO2N synthesized by the flux method when the impregnation-reduction method and the photodeposition method were sequentially applied.
As a result, the efficiency of the hydrogenation reaction using the BaTaO2N photocatalyst has been improved to nearly 100 times that of the conventional one, and the efficiency of the two-step excitation type (Z scheme type) water decomposition reaction in combination with the oxygen generation photocatalyst has also been improved.
Transient absorption spectroscopy reveals that the Pt-assisted catalyst microparticles supported by the new method are less likely to induce recombination of electrons and holes because they efficiently extract electrons from the BaTaO2N photocatalyst .
By supporting a small amount of Pt co-catalyst by the impregnation-reduction method in advance, the reduction reaction on the photocatalyst is promoted without agglutination of Pt fine particles. As a result, Pt cocatalyst fine particles are evenly supported by photodeposition on BaTaO2N particles. As a result, it is considered that the extraction of electricity by Pt co-catalyst fine granules proceeded efficiently.
It was also confirmed that the use of BaTaO2N, which is synthesized using an appropriate flux and has a low density of defects, is also important for supporting a highly dispersed Pt co-catalyst.
This study dramatically improved the activity of the BaTaO2N photocatalyst and clarified its mechanism. The results of this research are expected to lead to the development of long-wavelength-responsive photocatalysts that drive the water decomposition reaction with high efficiency.
Research Report: "Sequential cocatalyst decoration on BaTaO2N towards highly-active Z-scheme water splitting"
Related Links
Shinshu University
All About Solar Energy at SolarDaily.com
With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords.
Our news coverage takes time and effort to publish 365 days a year.
If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor